Frankly, I'm not seeing any painless way to get you to ZCS6 on SLES11...
Zimbra-to-Zimbra migrations require that both servers be running the same version of Zimbra. I don't believe ZCS6 runs on CentOS 4.3, but if ZCS 5 runs on CentOS 4.3 (I don't recall), you could build up the new server with SLES10-SP3 and ZCS 5, upgrade your existing box to ZCS 5, and then do the migration -- as a first step.
Next, you'd wipe the old box, install SLES10-SP3 and ZCS5, then upgrade to ZCS6.
Lastly, you'd wipe the new box, install SLES11 and ZCS6, and migrate one more time.
Alternatively, you could build the new box with SLES11 and ZCS6 and duplicate the accounts with a temporary, differing domain name. The users could use Outlook or any IMAP client to add the ZCS server to their client and drag 'n drop their emails over. They would use the ZCS web client to export their calendars and contacts from the old server and then you could import them into the new server.
Perhaps someone else can see a third, less painless way here, but since you've lost your Linux sysadmin, I'm leaving out things like impasync.
Hope that helps,
Mark
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