Q: Do you absolutely need to configure a brand new server, or can you use the old config/setup and do the blog method?
Might give us the exact zcs versions, operating systems, and your intent.
If you need to switch server operating system platform's you can still use the blog method:
/blog/archives/2007/10/moving_zcs_to_another_server.html
-Note how step 3 is install.sh -s which is used for the platform switch
-Platform doesn't matter, you just need to keep the zimbra version's the same (& note gid/uid's etc)
32bit > 64bit there's more needed however:
/blog/archives/2007/05/exporting_and_importing_zimbra_ldap_data_1.html
Or you could upgrade the 4.5.x box to NE first then use:
/docs/ne/latest/administration_guide/10_Backup_Restore.14.1.html CLI - zmbackup Network Edition Only - Zimbra :: Wiki CLI - zmbackup Network Edition Only - Zimbra :: Wiki
If those don't fit your situation you're left with imapsync, rest exports & curl imports:
User Migration - Zimbra :: Wiki
Do be sure to vote for
Bug 19630 - Migration Tool zimbra to zimbra