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The only officially supported HA is on RHCS and it's a Network Edition feature, if you want to do it with the Open Source version you should search the forums and wiki for 'DRBD' - that's a community supported feature and you may or may not find it easy to configure and get working. If you don't have it and your 'customer' is serious about a HA solution for his mail then I'd suggest you look at using RHCS with Zimbra Network Edition.