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We also encourage you to explore all things Zimbra with our team and members of the community.
We currently don't produce WinXP binaries or install. That said 99% of the dependancies are avail on Windows. Postfix is the only item that doesn't have a Windows port. If your a bit of a hacker take a look at ZimbraServer/docs/INSTALL.txt in the source download. This is how some of us do dev installs on our laptops. Not useful for a production install(no MTA) but will let you play with the UI and server code.