Zimbra will receive mail directly and it's delivered to each mailbox on the system, your users can access their mail (and all the ZImbra features) using the Web UI or any other client including the Zimbra Desktop. The Collaboration features used by Outlook will depend on whether you're talking about the Network Edition of ZImbra or the Open Source version. Mail clients can access the Zimbra server when the user has internet access and mail can be read offline.
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Regards
Bill
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