webman's description would do it. The mv command would do it fine though without permission loss.
Shutdown Zimbra first before moving files or remounting. Also make a backup if you can.
Quote:
mkdir /tempdir
mount /dev/sdx# here /tempdir
mv -R /opt/zimbra/* /tempdir
umount /tempdir
mount /dev/sdx# /opt/zimbra
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View mounted drives and available space.
If all looks good and the data is where it should be, restart Zimbra at this point and all should be well.