Sounds good. I'm not sure about the official compatability of any other version of Ubuntu than 6.06 though; but if it's working - that's good

What do you have in place for backup? Depending on disk usage it could be a problem if you create a localy copy of the Zimbra directory during backup.
This will eventually be a problem for us as time goes on; but will hopefully have some additional local disks and/or a SAN within the next 6 months.
Yes, I would definitely throw another 2GB of RAM into the Zimbra server to take it up to 4GB - it should perform much better. (Many threads on the forum that can confirm bumping up the RAM makes it quicker)