I think he has general send/receive of mail? (I keep mentioning the dns checks-but him and john were working on it last night, and might have specifically set dns checks off?)
If you're talking about a relay
Outgoing SMTP Authentication - Zimbra :: Wiki check your value's of these across the board
smtpd_use_tls
smtpd_tls_auth_only
smtpd_tls_key_file = /opt/zimbra/conf/smtpd.key
smtpd_tls_cert_file = /opt/zimbra/conf/smtpd.crt
If you want to get some more output:
smtp_tls_loglevel
0 Disable logging of TLS activity.
1 Log TLS handshake and certificate information. (what you have currently)
2 Log levels during TLS negotiation.
3 Log hexadecimal and ASCII dump of TLS negotiation process.
4 Log hexadecimal and ASCII dump of complete transmission after STARTTLS.