I don't think that you would want to do block all messages from POSTMASTER or MAILER-DAEMON. People need to know that their mail is bouncing, but I agree that this is particular example is a problem.
We have a similar issue happening and what we've done so far is tell the user to stop forwarding their mail to the external address and then block that external account on our spam filter appliances.
Sorry I don't have any solution to add.
