First of all you should search the forums for 32 to 64 bit migration/move
you will find lots of message where people have done this sucssfully.
or simple google search
http://www.google.com/#hl=en&&sa=X&e...9f310bee2047fa
main thing to understand is the LDAP migration..you should read some messages in the search to see what problems they faced and the solutions suggesed
the 95% of the migration is explained in the link below
http://blog.zimbra.com/blog/archives...er-server.html
rest please read the other messages to tweak the process for 32 > 64 bit
Raj