Thanks for the suggestions on the best ways to replicate the servers. The reason I asked about this is that creating a clustered file system on a SAN will not allow me to test upgrades, patches without changing the whole system at once, thus the motivation to have a cold standby.
Just for reference, I did find a script that shows how to copy over the MySQL dbs: the script dumprestore.sh at:
Harley77-Backup - Zimbra :: Wiki
which shows how to use a loop to back up the zimbra and the mbox MySQL dbs and restore them.