Some ideas:
-A thick client with sent confirmation/delivery confirmation/read receipts turned on?
-Seems odd that it's just with attachments unless going through a scanner somewhere causes the DSN not to work. (Of if it's getting marked as spam and there's a cutoff level for not sending DSN's that it's hitting because of the attachments.)
-You could create a custom bounce.cf for postfix in your language.
-Does this only happen when you email external addresses or does it also happen for internal accounts?
Quote:
#The success template is used when mail is delivered to mailbox, when an alias or list is expanded, or when mail is delivered to a system that does not announce DSN support.
success_template = <<EOF
Charset: us-ascii
From: MAILER-DAEMON (Mail Delivery System)
Subject: Successful Mail Delivery Report
This is the mail system at host $myhostname.
Your message was successfully delivered to the destination(s) listed below. If the message was delivered to mailbox you will receive no further notifications. Otherwise you may still receive notifications of mail delivery errors from other systems.
The mail system
EOF
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