I'm still pretty much a qmail guy, but need to pick up some postfix skills, so I'm not entirely sure about this solution, but it looks like the general idea would be something along these lines:
In your main.cf for postfix add a line / add to the restrictions line if its there already:
smtpd_client_restrictions = permit_mynetworks
this will hopefully override the RBL checks for all ip ranges you have in $mynetworks. Add your ADSL ip ranges to that, and hopefully all goes well.
Reference:
Postfix Configuration - UCE Controls