The obvious question is: is the FQDN of your Zimbra server actually postmaster.usys.com? It seems to not exists as far as DNS is concerned:
Quote:
Creating server entry for postmaster.usys.com...
*** Running as zimbra user: /opt/zimbra/bin/zmprov -l cs postmaster.usys.com
ERROR: service.FAILURE (system failure: createServer) (cause: javax.naming.NamingException [LDAP: error code 80 - internal error])
Done
Setting spell check URL...
*** Running as zimbra user: /opt/zimbra/bin/zmprov -l ms postmaster.usys.com zimbraSpellCheckURL http://postmaster.usys.com:7780/aspell.php
ERROR: service.FAILURE (system failure: unable to lookup server by name: postmaster.usys.com message: [LDAP: error code 80 - internal error]) (cause: javax.naming.NamingException [LDAP: error code 80 - internal error])
Done
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You need to check you /etc/hosts file for correct entries, you also need to fix the DNS entries. Search the forums for 'DNS in a Nutshell' and follow the instructions there (it's also in the wiki). If you're behind a NAT device then you probably need a split-DNS setup to resolve the server IP correctly - details also in the wiki for that.
This
check on your DNS shows no server by the name postmaster.usys.com.