It looks like your replica does not load the same schema files as your master, thus replication will never occur to it. Fix what schema are allowed.
Quote:
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Jun 12 16:01:39 slave slapd[6797]: syncrepl_message_to_entry: rid 100 mods check (sambaDomainName: attribute type undefined)
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You can clearly see the samba schema is in place on your master.